Figure 1 Cyclic voltammograms obtained from an electrolyte of 1 mmol dm−3 [Ru(NH3 )6]3+ in 0.1 M NaNO3 in aqueous solution on a bare ITO substrate (black) on a mesoporous silica film with surfactant (red) and  on a mesoporous silica film without surfactant(blue).

Columns x1 and y1 (on a bare ITo substrate): X1 axis: Potential vs. Ag/AgCl / V  Y1 axis: Current density mA
Columns x2 and y2 (on a mesoporous silica film with surfactant ): X2 axis: Potential vs. Ag/AgCl / V  Y2 axis: Current density mA
Columns x3 and y3 (on a mesoporous silica film without surfactant) X3 axis: Potential vs. Ag/AgCl / V  Y3 axis: Current density mA
	
x1	y1	x2      y2      x3      y3
0.1548	0.02602	0.0737	0.00169	0.15297	0.03465
0.1553	0.0258	0.07426	0.00171	0.15356	0.03479
0.15635	0.02571	0.07529	0.00171	0.15452	0.03464
0.15732	0.02561	0.07625	0.00171	0.15553	0.03448
0.15834	0.02553	0.07724	0.00171	0.15652	0.03435
0.15937	0.02543	0.07827	0.00171	0.15755	0.03419
0.16033	0.02532	0.07931	0.00171	0.15854	0.03404
0.1613	0.02524	0.0803	0.00171	0.15955	0.03393
0.16231	0.02512	0.08127	0.00171	0.16051	0.03375
0.1633	0.02502	0.08229	0.0017	0.16153	0.03362
0.16429	0.02495	0.08327	0.0017	0.16252	0.03346
0.16532	0.02484	0.08431	0.0017	0.16352	0.03332
0.16629	0.02477	0.08528	0.0017	0.16451	0.03322
0.1673	0.02468	0.08626	0.00169	0.16551	0.03307
0.16834	0.02457	0.08725	0.00169	0.16653	0.03293
0.16933	0.02451	0.0883	0.00169	0.16752	0.0328
0.17036	0.02441	0.08928	0.00169	0.16855	0.03265
0.17136	0.02431	0.09025	0.00169	0.16954	0.03254
0.17232	0.02422	0.09129	0.00169	0.17056	0.0324
0.17333	0.02412	0.09229	0.00169	0.17154	0.03224
0.17434	0.02403	0.09331	0.00169	0.17257	0.03214
0.17533	0.02394	0.09432	0.00169	0.1736	0.03201
0.1763	0.02386	0.09534	0.00168	0.17459	0.03187
0.17733	0.02379	0.09632	0.00168	0.1756	0.03172
0.17833	0.0237	0.0973	0.00168	0.17654	0.03161
0.17932	0.02361	0.0983	0.00168	0.17753	0.03149
0.18034	0.02354	0.09929	0.00167	0.17857	0.03138
0.1813	0.02344	0.10032	0.00167	0.17954	0.03123
0.18234	0.02339	0.10131	0.00167	0.18053	0.03114
0.18332	0.02329	0.1023	0.00167	0.18153	0.03102
0.18432	0.02319	0.10331	0.00167	0.18258	0.03088
0.18531	0.02313	0.10432	0.00167	0.18355	0.03078
0.18635	0.02303	0.10527	0.00166	0.18456	0.03063
0.18733	0.02295	0.10629	0.00166	0.18557	0.03053
0.18833	0.02285	0.1073	0.00166	0.18652	0.03041
0.1893	0.02279	0.10831	0.00166	0.18753	0.03028
0.19031	0.02273	0.10928	0.00166	0.18855	0.03016
0.19128	0.02264	0.11029	0.00166	0.18951	0.03007
0.1923	0.02256	0.11129	0.00165	0.19055	0.02994
0.19334	0.02251	0.11231	0.00165	0.19154	0.02986
0.19433	0.02243	0.11327	0.00165	0.19255	0.02972
0.19537	0.02234	0.11427	0.00165	0.19353	0.02962
0.19634	0.02227	0.11526	0.00165	0.19453	0.02953
0.19736	0.0222	0.11626	0.00165	0.19554	0.02939
0.19835	0.02213	0.11727	0.00165	0.19663	0.02929
0.19935	0.02206	0.11829	0.00165	0.19757	0.02917
0.19996	0.02211	0.11929	0.00164	0.19859	0.02906
0.20007	0.02205	0.12029	0.00164	0.19964	0.02897
0.19942	0.0203	0.1213	0.00164	0.20009	0.02868
0.19844	0.01995	0.12232	0.00164	0.19955	0.02664
0.19746	0.01976	0.1233	0.00164	0.19849	0.02636
0.19642	0.01962	0.12429	0.00163	0.19758	0.02619
0.19539	0.01951	0.12526	0.00163	0.19649	0.02605
0.19441	0.01934	0.12627	0.00163	0.19555	0.02592
0.19342	0.01926	0.12728	0.00163	0.1945	0.02576
0.19241	0.01914	0.12828	0.00163	0.19353	0.02568
0.19141	0.01904	0.12933	0.00163	0.1925	0.02555
0.19042	0.01894	0.13033	0.00163	0.19151	0.02542
0.1894	0.01883	0.13134	0.00163	0.19054	0.02533
0.1884	0.01877	0.13229	0.00162	0.1895	0.02518
0.18742	0.01866	0.13327	0.00162	0.18852	0.02511
0.18646	0.01856	0.13429	0.00162	0.18752	0.025
0.18546	0.01847	0.13532	0.00162	0.18653	0.02487
0.18441	0.01838	0.13633	0.00162	0.18552	0.02478
0.18346	0.01828	0.13731	0.00161	0.18452	0.02467
0.18242	0.01819	0.13832	0.00161	0.18355	0.02455
0.18143	0.01808	0.1393	0.00161	0.18252	0.02445
0.1804	0.01801	0.1403	0.00161	0.18152	0.02432
0.1794	0.01794	0.14133	0.00161	0.18053	0.02423
0.17842	0.01783	0.1423	0.00161	0.17953	0.02414
0.17742	0.01776	0.1433	0.00161	0.17852	0.02403
0.17641	0.01768	0.14428	0.00161	0.17754	0.02393
0.17542	0.01762	0.14534	0.00161	0.17651	0.02383
0.17442	0.01751	0.14634	0.0016	0.17553	0.02375
0.17341	0.01743	0.14734	0.0016	0.17451	0.02364
0.17238	0.01736	0.14831	0.0016	0.17353	0.02354
0.1714	0.01728	0.14935	0.0016	0.17253	0.02344
0.17043	0.01719	0.1503	0.00159	0.1715	0.02335
0.16942	0.01712	0.15133	0.00159	0.17057	0.02324
0.16841	0.01703	0.15232	0.00159	0.16955	0.02317
0.1674	0.01696	0.15332	0.00159	0.16852	0.02304
0.16638	0.01689	0.1543	0.00159	0.16748	0.02296
0.1654	0.0168	0.15531	0.00159	0.16652	0.02289
0.1644	0.01674	0.15629	0.00159	0.16551	0.02278
0.16339	0.01669	0.15731	0.00158	0.16449	0.02271
0.16239	0.01662	0.1583	0.00158	0.16348	0.02261
0.1614	0.01653	0.15932	0.00158	0.16253	0.02253
0.16039	0.01645	0.16027	0.00158	0.16155	0.02244
0.15939	0.01637	0.16133	0.00158	0.16053	0.02234
0.15843	0.01632	0.16233	0.00158	0.15951	0.02225
0.15742	0.01624	0.1633	0.00157	0.15852	0.02217
0.15638	0.01617	0.16428	0.00157	0.15752	0.02205
0.15538	0.01611	0.16529	0.00157	0.15649	0.02199
0.15442	0.01603	0.1663	0.00157	0.15552	0.0219
0.15337	0.01597	0.16732	0.00157	0.15455	0.02181
0.15237	0.0159	0.16828	0.00157	0.15352	0.02174
0.15138	0.01582	0.16933	0.00157	0.15252	0.02165
0.15042	0.01577	0.17032	0.00157	0.15153	0.02155
0.14948	0.01572	0.17133	0.00157	0.15051	0.02148
0.14841	0.01564	0.1723	0.00157	0.14954	0.02141
0.14739	0.01558	0.1733	0.00156	0.14854	0.02129
0.1464	0.01551	0.17436	0.00156	0.14751	0.02122
0.14541	0.01545	0.17531	0.00156	0.14654	0.02113
0.14441	0.0154	0.17629	0.00156	0.14553	0.02108
0.14342	0.0153	0.17733	0.00156	0.14453	0.02097
0.14237	0.01526	0.1783	0.00156	0.14354	0.02087
0.14139	0.01519	0.17927	0.00156	0.14251	0.02081
0.14038	0.01513	0.18032	0.00156	0.1415	0.02073
0.13939	0.01508	0.18131	0.00155	0.1405	0.02066
0.1384	0.01501	0.18231	0.00156	0.1395	0.02058
0.13741	0.01496	0.18332	0.00155	0.13851	0.02048
0.13638	0.01491	0.18432	0.00155	0.13751	0.02042
0.13536	0.01484	0.18531	0.00155	0.13649	0.02035
0.13441	0.01479	0.18632	0.00155	0.1355	0.02026
0.13342	0.01472	0.18737	0.00155	0.13453	0.02018
0.13242	0.01466	0.18828	0.00154	0.13353	0.0201
0.13143	0.01462	0.18932	0.00154	0.13248	0.02002
0.13037	0.01452	0.1903	0.00154	0.13149	0.01995
0.12941	0.0145	0.19131	0.00154	0.13049	0.01983
0.12838	0.01444	0.19233	0.00154	0.12951	0.0198
0.1274	0.01437	0.1933	0.00154	0.12849	0.01972
0.12641	0.01433	0.19431	0.00154	0.12745	0.01962
0.12539	0.01426	0.19536	0.00154	0.12646	0.01957
0.12441	0.01424	0.19635	0.00154	0.12547	0.01948
0.12338	0.01419	0.19734	0.00153	0.12448	0.01942
0.12238	0.01409	0.19835	0.00153	0.12348	0.01936
0.12138	0.01406	0.19933	0.00153	0.12251	0.01925
0.12039	0.01401	0.1999	0.00157	0.12151	0.0192
0.1194	0.01394	0.20007	0.00157	0.1205	0.01912
0.11838	0.01389	0.19953	0.00132	0.11955	0.01903
0.11736	0.0138	0.19855	0.00109	0.11855	0.01897
0.11638	0.01378	0.19758	9.36137E-4	0.11747	0.01886
0.11539	0.01375	0.19657	8.21642E-4	0.11647	0.01882
0.11436	0.01368	0.19549	7.31496E-4	0.11544	0.01875
0.11337	0.01364	0.19449	6.49672E-4	0.11448	0.01867
0.11237	0.01358	0.19354	5.85948E-4	0.11347	0.01862
0.11138	0.01353	0.19249	5.28771E-4	0.11247	0.01852
0.11041	0.01348	0.19151	4.804E-4	0.11146	0.01849
0.10935	0.01342	0.19053	4.35615E-4	0.11047	0.01839
0.10838	0.01337	0.1895	3.95267E-4	0.10948	0.01829
0.10738	0.01332	0.18852	3.62816E-4	0.10849	0.01824
0.10639	0.01327	0.18753	3.31208E-4	0.10749	0.01819
0.10542	0.01323	0.18651	2.9956E-4	0.10654	0.01808
0.10439	0.01318	0.18555	2.75163E-4	0.10553	0.01803
0.10338	0.01312	0.18449	2.48318E-4	0.10447	0.01795
0.10239	0.01309	0.18357	2.26575E-4	0.1035	0.01786
0.10139	0.01302	0.18253	2.0546E-4	0.10252	0.01781
0.10037	0.01298	0.18153	1.81946E-4	0.10149	0.01773
0.09942	0.01295	0.18049	1.64958E-4	0.1005	0.01768
0.09843	0.01289	0.17951	1.46118E-4	0.09947	0.01759
0.09741	0.01284	0.1785	1.31098E-4	0.09853	0.01753
0.09641	0.0128	0.17751	1.16729E-4	0.0975	0.01746
0.0954	0.01273	0.17648	9.9295E-5	0.09647	0.01738
0.09437	0.0127	0.17549	8.95725E-5	0.0955	0.01729
0.09337	0.01264	0.17452	7.74053E-5	0.09449	0.01724
0.09242	0.01259	0.17354	6.26778E-5	0.09348	0.01715
0.09138	0.01256	0.17256	4.98715E-5	0.09248	0.01707
0.0904	0.01249	0.17149	3.95601E-5	0.09146	0.01701
0.08935	0.01246	0.17053	2.66211E-5	0.09048	0.01693
0.08835	0.01241	0.16953	1.75351E-5	0.08948	0.01688
0.08737	0.01235	0.16851	2.87835E-6	0.08846	0.01679
0.08638	0.01233	0.16748	-3.88951E-6	0.08748	0.0167
0.08538	0.01229	0.16648	-1.28491E-5	0.08647	0.01666
0.08438	0.01223	0.16551	-2.42223E-5	0.08548	0.01659
0.08339	0.01219	0.16447	-3.11245E-5	0.0845	0.0165
0.0824	0.01213	0.16345	-3.79036E-5	0.0835	0.01643
0.0814	0.01209	0.16248	-4.37664E-5	0.0825	0.01634
0.08042	0.01204	0.16152	-5.09401E-5	0.0815	0.01627
0.07938	0.01198	0.16049	-6.20799E-5	0.08049	0.01619
0.07839	0.01195	0.15949	-6.74049E-5	0.07949	0.0161
0.0773	0.01191	0.1585	-7.43929E-5	0.07849	0.01603
0.07639	0.01186	0.15751	-8.25373E-5	0.07747	0.01594
0.07538	0.01182	0.15649	-8.71338E-5	0.07645	0.01588
0.07428	0.01176	0.15553	-9.49803E-5	0.07548	0.01581
0.0734	0.01173	0.15451	-1.02814E-4	0.07446	0.01572
0.07237	0.0117	0.15347	-1.06021E-4	0.0735	0.01565
0.07136	0.01162	0.15253	-1.14773E-4	0.07245	0.01559
0.07038	0.0116	0.15151	-1.19795E-4	0.07145	0.01547
0.0694	0.01154	0.15051	-1.25224E-4	0.07049	0.0154
0.0684	0.0115	0.14955	-1.29595E-4	0.06946	0.01531
0.06739	0.01146	0.14852	-1.33903E-4	0.06849	0.01524
0.06637	0.01138	0.1475	-1.41469E-4	0.06751	0.01515
0.06536	0.01136	0.14652	-1.48016E-4	0.0665	0.01502
0.06437	0.01132	0.14552	-1.52062E-4	0.06543	0.01499
0.06332	0.01127	0.14454	-1.59332E-4	0.06444	0.01488
0.06233	0.01122	0.14349	-1.65038E-4	0.06344	0.0148
0.06133	0.01117	0.14253	-1.7078E-4	0.06245	0.01471
0.06035	0.01114	0.14145	-1.75565E-4	0.06146	0.0146
0.05937	0.01109	0.14051	-1.80094E-4	0.06051	0.01455
0.05839	0.01104	0.13949	-1.83551E-4	0.05946	0.01445
0.05737	0.01099	0.13848	-1.88371E-4	0.05846	0.01433
0.0564	0.01095	0.13751	-1.91895E-4	0.05746	0.01426
0.0553	0.01088	0.1365	-1.93875E-4	0.05649	0.01413
0.05436	0.01085	0.13552	-1.99574E-4	0.05547	0.01404
0.05337	0.0108	0.13453	-2.04723E-4	0.05446	0.01395
0.05239	0.01075	0.13351	-2.07027E-4	0.0535	0.01385
0.05139	0.01071	0.13252	-2.11323E-4	0.05249	0.01373
0.05035	0.01065	0.13154	-2.17017E-4	0.05147	0.01364
0.04933	0.01061	0.13051	-2.22219E-4	0.05045	0.01349
0.04835	0.01056	0.12948	-2.24858E-4	0.04948	0.01342
0.04738	0.01051	0.1285	-2.3123E-4	0.04848	0.01331
0.04635	0.01046	0.12751	-2.33615E-4	0.04745	0.01321
0.04534	0.0104	0.12649	-2.3802E-4	0.04648	0.01308
0.04436	0.01035	0.12549	-2.41329E-4	0.04546	0.01295
0.04334	0.01029	0.12448	-2.43347E-4	0.04446	0.01283
0.0424	0.01024	0.1235	-2.46544E-4	0.04349	0.01271
0.04134	0.01018	0.12249	-2.50658E-4	0.04249	0.01256
0.04038	0.01012	0.12152	-2.5462E-4	0.0415	0.01245
0.03934	0.01007	0.12048	-2.58337E-4	0.04045	0.01228
0.03833	0.01002	0.11947	-2.62362E-4	0.03948	0.01217
0.03731	0.00996	0.11851	-2.65706E-4	0.03839	0.01205
0.03636	0.0099	0.11746	-2.7327E-4	0.03743	0.01188
0.03536	0.00986	0.11647	-2.76084E-4	0.03644	0.01175
0.03438	0.00979	0.11543	-2.78302E-4	0.03545	0.01161
0.03336	0.00972	0.11448	-2.80929E-4	0.03447	0.01149
0.03236	0.00966	0.11345	-2.83451E-4	0.03342	0.01131
0.03135	0.00959	0.11247	-2.87228E-4	0.0325	0.01113
0.03036	0.00954	0.11144	-2.88079E-4	0.03146	0.01098
0.02936	0.00947	0.11048	-2.90403E-4	0.03049	0.01082
0.02841	0.00938	0.10946	-2.95961E-4	0.02948	0.01061
0.02732	0.00933	0.10849	-2.9838E-4	0.02846	0.01045
0.02634	0.00925	0.10748	-3.0187E-4	0.02747	0.01027
0.02538	0.0092	0.10651	-3.0622E-4	0.02646	0.01007
0.02434	0.00912	0.10547	-3.09203E-4	0.02543	0.00991
0.02334	0.00904	0.10449	-3.11374E-4	0.02447	0.0097
0.02235	0.00898	0.10346	-3.1332E-4	0.02343	0.00948
0.02139	0.00892	0.10251	-3.19872E-4	0.02243	0.00932
0.02034	0.00881	0.10145	-3.22332E-4	0.02148	0.00912
0.01935	0.00874	0.10047	-3.23608E-4	0.02045	0.00887
0.01836	0.00864	0.09948	-3.27048E-4	0.01945	0.00865
0.01737	0.00858	0.09852	-3.27621E-4	0.01846	0.0084
0.01635	0.00848	0.0975	-3.289E-4	0.01743	0.00816
0.01531	0.00836	0.09648	-3.35432E-4	0.01642	0.00791
0.01434	0.0083	0.0955	-3.38357E-4	0.01543	0.00763
0.01334	0.0082	0.09452	-3.40918E-4	0.01446	0.0074
0.01233	0.00812	0.0935	-3.44765E-4	0.01343	0.0071
0.01134	0.00803	0.09248	-3.48222E-4	0.0124	0.00687
0.01033	0.00791	0.09149	-3.54301E-4	0.01146	0.00658
0.00927	0.00782	0.09045	-3.56055E-4	0.01041	0.00628
0.00837	0.00773	0.08947	-3.57261E-4	0.00941	0.006
0.00734	0.0076	0.08847	-3.62987E-4	0.00846	0.00574
0.00639	0.0075	0.08747	-3.63665E-4	0.00746	0.00538
0.00537	0.00737	0.08648	-3.66178E-4	0.00646	0.00506
0.00441	0.00726	0.0855	-3.65579E-4	0.00544	0.0047
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0.09049	0.03782	-2.32745E-4	0.00178	0.08808	0.05199
0.09152	0.03763	7.46422E-4	0.00178	0.08906	0.05173
0.09253	0.03748	0.0018	0.00178	0.09007	0.0514
0.09349	0.03729	0.00275	0.00178	0.09114	0.05114
0.09454	0.03712	0.00379	0.00178	0.09208	0.0509
0.09554	0.03695	0.00478	0.00178	0.09312	0.05055
0.0965	0.03677	0.00574	0.00178	0.0941	0.05036
0.09753	0.03661	0.00674	0.00178	0.09509	0.05002
0.09854	0.03641	0.00775	0.00178	0.09614	0.04977
0.0995	0.03625	0.00873	0.00178	0.0971	0.0495
0.1005	0.03611	0.00974	0.00178	0.09808	0.04924
0.10154	0.03595	0.01075	0.00178	0.09909	0.04895
0.10252	0.03578	0.01169	0.00178	0.10011	0.0487
0.10348	0.03562	0.01274	0.00178	0.10107	0.04843
0.10446	0.03545	0.01375	0.00178	0.10208	0.0482
0.10549	0.03532	0.01472	0.00178	0.1031	0.04798
0.10653	0.03516	0.01576	0.00178	0.10409	0.04771
0.1075	0.035	0.01675	0.00178	0.10593	0.04697
0.10851	0.03485	0.01778	0.00178	0.10772	0.04636
0.10951	0.0347	0.01878	0.00178	0.10874	0.04612
0.11054	0.03454	0.01977	0.00178	0.10971	0.0459
0.1115	0.03437	0.02074	0.00178	0.11071	0.04566
0.11248	0.03425	0.02175	0.00178	0.11171	0.04542
0.11351	0.0341	0.02278	0.00177	0.11267	0.04523
0.11449	0.03395	0.02374	0.00178	0.11369	0.04498
0.11548	0.03381	0.02478	0.00178	0.11468	0.04478
0.1165	0.03368	0.02575	0.00178	0.11573	0.04454
0.11749	0.03354	0.02675	0.00178	0.11669	0.04435
0.11849	0.03339	0.02776	0.00177	0.11769	0.04416
0.11952	0.03326	0.02878	0.00178	0.11877	0.04391
0.12052	0.03312	0.02977	0.00177	0.11977	0.04373
0.1215	0.03298	0.03077	0.00177	0.12075	0.04352
0.12254	0.03284	0.03176	0.00177	0.12177	0.04329
0.1235	0.03269	0.03277	0.00177	0.12277	0.04311
0.1245	0.03254	0.03378	0.00177	0.12375	0.04288
0.12547	0.03245	0.03474	0.00177	0.12468	0.04269
0.1265	0.03231	0.03577	0.00177	0.12573	0.04249
0.12748	0.03219	0.03675	0.00177	0.12674	0.04229
0.12849	0.03204	0.03776	0.00177	0.12775	0.04212
0.12953	0.03193	0.03875	0.00177	0.12873	0.04192
0.1305	0.03181	0.03978	0.00177	0.12972	0.04172
0.13154	0.03167	0.04078	0.00176	0.13074	0.04156
0.1325	0.03156	0.04177	0.00176	0.13171	0.04134
0.13353	0.03144	0.0428	0.00176	0.13271	0.04117
0.1345	0.0313	0.04382	0.00176	0.13369	0.04099
0.13552	0.0312	0.04478	0.00176	0.13469	0.0408
0.13653	0.03106	0.04579	0.00176	0.13573	0.04064
0.13753	0.03093	0.04677	0.00176	0.13676	0.04042
0.1385	0.03083	0.04779	0.00175	0.13771	0.04025
0.1395	0.0307	0.04878	0.00175	0.13875	0.0401
0.14047	0.03058	0.04979	0.00175	0.13974	0.03992
0.1415	0.03047	0.05078	0.00175	0.14073	0.03975
0.1425	0.03034	0.05176	0.00175	0.14172	0.03958
0.14349	0.03027	0.05273	0.00175	0.14271	0.0394
0.14454	0.03013	0.05376	0.00175	0.14373	0.03928
0.14553	0.03002	0.05477	0.00175	0.14471	0.03909
0.14652	0.02991	0.05574	0.00175	0.14573	0.0389
0.14756	0.02979	0.05675	0.00175	0.14675	0.03876
0.14853	0.02969	0.05777	0.00174	0.14775	0.03858
0.14953	0.02956	0.05883	0.00175	0.14873	0.03841
0.15055	0.02945	0.05976	0.00174	0.14973	0.03824
0.15149	0.02937	0.06075	0.00174	0.15079	0.0381
0.15253	0.02925	0.06178	0.00174	0.15174	0.03797
0.15351	0.02914	0.06274	0.00174	0.15252	0.03766
0.15433	0.02909	0.06376	0.00174	0.15289	0.03822